Geochemic Ltd

Geochemic Ltd


What is Acid Rock Drainage

Acid Rock Drainage (ARD) is formed when a rock mass containing sulfide minerals weathers in the presence of oxygen and moisture. This process of oxidative weathering can result in the releases of sulfuric acid and associated metals into the environment.

ARD occurs naturally through the weathering and erosion of sulfide rich rocks. Sulfide minerals commonly occur in close association with commercially valuable mineral deposits such as gold, copper, zinc and iron. For this reason the natural process of weathering may be significantly accelerated through mining processes. Acid Mine Drainage (AMD) is commonly used to describe ARD resulting primarily from mining processes. 

The acid produced during ARD / AMD  is sulfuric acid (H2SO4). This is the same type of acid as used in car batteries and in some cases the acid concentration ("strength") can be similar. It is common for ARD / AMD to be accompanied with toxic concentrations of metals such as arsenic, aluminium, cadmium, copper, iron, lead, nickel, and zinc. These metals are often contained within sulfide minerals themselves (i.e. zinc within sphalerite) and are released from the mineral during the weathering process. In addition, as the solution becomes more acidic (the pH decreases) an increasing concentration of metals may be dissolved in the water and released into the environment. Due to the potential for metals leaching, ML is commonly added after ARD or AMD (i.e. Acid Rock Drainage and Metal Leaching).

The term acid can be misleading as not all sulfide minerals generate acidity when they oxidise, in addition, acidity that may be generated may rapidly be neutralised through acid-neutralization reactions. Carbonate minerals such as calcite (CaCO3) are the most common neutralising minerals and in some cases can be present together with acid generating sulfide minerals. Carbonate minerals readily dissolve neutralising acidity through the release of carbonate ions into solution. Carbonate neutralisation often results in a neutral pH solution and limits the dissolved concentrations of many potentially toxic metals through mineral precipitation and adsorption of metals to mineral surfaces.

Photo by
Cookie settings
This site uses cookies to offer you a better browsing experience.
You can accept them all, or choose the kinds of cookies you are happy to allow.
Privacy settings
Choose which cookies you wish to allow while you browse this website. Please note that some cookies cannot be turned off, because without them the website would not function.
To prevent spam this site uses Google Recaptcha in its contact forms.

This site may also use cookies for ecommerce and payment systems which are essential for the website to function properly.
Google Services
This site uses cookies from Google to access data such as the pages you visit and your IP address. Google services on this website may include:

- Google Analytics
- Google Ads conversion tracking
- Google Maps
Data Driven
This site may use AddThis:
- AddThis is a social widget which collects and shares user behavior with third parties.